THE 2-METHYLBUT-2-ENYL(DIPHENYL)SILYL GROUP - A SILYL GROUP EASILY CONVERTED TO HYDROXYL IN THE PRESENCE OF A 1,2-DISUBSTITUTED C=C DOUBLE-BOND

被引：40

作者：

FLEMING, I

WINTER, SBD

机构：

[1] Department of Chemistry, Cambridge, CB2 1EW England, Lensfield Road

来源：

TETRAHEDRON LETTERS | 1993年 / 34卷 / 45期

关键词：

D O I：

10.1016/S0040-4039(00)79310-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The 2-methylbut-2-enyl(diphenyl)silyl group can be introduced into a variety of organic structures by way of the cuprate reagent 4, and it can then be converted into a hydroxyl group, even in the presence of a C=C double bond, unlike the dimethyl(phenyl)silyl group.

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页码：7287 / 7290

页数：4

相关论文

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