GYROMAGNETIC FACTORS AND COVALENCY IN TETRAHEDRAL D5-COMPLEXES

被引：23

作者：

KANDEL, LD

PASSEGGI, MC

BUCH, T

机构：

[1] Departamento de Química, Facultad de Ciencias, Universidad de Chile

来源：

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS | 1969年 / 30卷 / 02期

关键词：

D O I：

10.1016/0022-3697(69)90313-8

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

g-Factors of Fe(III) complexes with different heavy ligands in tetrahedral symmetry differ substantially from the free-electron value, expected for such systems. The g-shifts are satisfactorily explained by important contributions of ligand spin-orbit coupling in the presence of a large degree of covalency. © 1969.

引用

页码：321 / &

共 23 条

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