BIOSYNTHESIS OF CHIMONANTHINE FROM [2-3H]TRYPTOPHAN AND [2-3H]-TRYPTAMINE

被引：22

作者：

KIRBY, GW

SHAH, SW

HERBERT, EJ

机构：

[1] Chemistry Department, University of Technology, Loughborough

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 14期

关键词：

D O I：

10.1039/j39690001916

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Conversion of (±)-[β-14C, 2-3H]tryptophan and [β-14C, 2-3H]tryptamine into (-)-chimonanthine has been shown to occur in Chimonanthus fragrans (praecox) without loss of tritium. Degradation of the alkaloid has established the predicted labelling pattern. A synthesis of [2-3H]- and [2-3H]-indole from indoxyl is recorded and the structure of diacetoxymercuri-indole is revised.

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页码：1916 / &

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