CONJUGATED ADDITIONS IN HYDROGEN FLUORIDE

被引：12

作者：

GERMAN, LS

KNUNYANT.IL

机构：

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1969年 / 8卷 / 05期

关键词：

Addition; Fluorination; Fluorine; Hydrogen fluoride; Solvents;

D O I：

10.1002/anie.196903491

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fluorine and another substituent can be added in a single step to compounds having CC double bonds in anhydrous hydrogen fluoride. It is possible in this way to obtain e.g. α‐fluorinated β‐halogeno, β‐alkyl, β‐nitro, and β‐amino compounds, and also (in some cases by secondary reactions) fluorinated ethers, alcohols, esters, and carboxylic acids, β‐fluoro alcohols can be obtained by conjugated “hypofluorination” in the presence of oxenium ions. Copyright © 1969 by Verlag Chemie, GmbH, Germany

引用

页码：349 / &

共 54 条

[1]

BARENDRECHT W, 1958, CHEM WEEKBL, V54, P404

[2] The mechanism of addition reactions. A kinetic study of the addition of methyl hypobromite to stilbene [J].