COMPLEX CATALYST STUDIES OF ZIEGLER-NATTA TYPE .2. OXIDATION-REDUCTION REACTION IN THE IRON STEARATE-TRIETHYLALUMINUM SYSTEM

被引：14

作者：

BRODSKII, AR ^{[1
]}

VOZDVIZHENSKII, VF ^{[1
]}

NOSKOVA, NF ^{[1
]}

KHLYSTOV, AS ^{[1
]}

PAKHORUKOVA, OM ^{[1
]}

SOKOLSKII, DV ^{[1
]}

机构：

[1] ACAD SCI KASSR,INST ORGAN CATALYSIS & ELECTROCHEM,ALMA ATA 480021,KASSR

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 179卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)95215-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

At molar ratios of ≤2 Al(C2H5)3:≤ 4 Fe(C17H35COO)3 complexes containing iron(III) and iron(II) are formed as a result of redox transformations. With an increase in Al : Fe, multinuclear associated systems result, in which iron(III) and iron(II) are bound to alkylaluminium. A further increase in concentration of AlR3 leads to only an increase in the size of associates due to alkylaluminium coordination. © 1979.

引用

页码：139 / 143

页数：5