POLYMERIC LIGANDS .9. OXIDATION-REDUCTION PROPERTIES OF SOME POLYMERIC THIOSEMICARBAZIDES CONTAINING COPPER IONS

被引：9

作者：

DONARUMA, LG

KITOH, S

WALSWORTH, G

DEPINTO, JV

EDZWALD, JK

机构：

[1] CLARKSON COLL TECHNOL,DEPT CIVIL & ENVIRONM ENGN,POTSDAM,NY 13676

[2] CLARKSON COLL TECHNOL,DEPT CHEM,POTSDAM,NY 13676

来源：

MACROMOLECULES | 1979年 / 12卷 / 03期

关键词：

D O I：

10.1021/ma60069a018

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The syntheses of three new poly(thiosemicarbazides) are reported along with those of the respective copper(I) and copper (II) complexes. Oxidation-reduction reactions of the copper complexes of five polymeric thiosemicarbazides, wherein the Cu(I)-Cu(II) “redox” system was employed to reduce or oxidize various organic substrates, are described. “Redox” properties appeared to be related to the nature of the polymer employed to hold the copper. © 1979, American Chemical Society. All rights reserved.

引用

页码：435 / 438

页数：4

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