QUENCHING MECHANISM IN A HIGHLY EXOTHERMIC REGION OF THE REHM-WELLER RELATIONSHIP FOR ELECTRON-TRANSFER FLUORESCENCE QUENCHING

被引：93

作者：

KIKUCHI, K

NIWA, T

TAKAHASHI, Y

IKEDA, H

MIYASHI, T

机构：

[1] Department of Chemistry, Faculty of Science, Tohoku University, Aoba, Aramaki, Aoba-ku

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1993年 / 97卷 / 19期

关键词：

D O I：

10.1021/j100121a037

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The fluorescence quenching mechanism in a highly exothermic region of the Rehm-Weller relationship is shown to be a long-distance electron transfer for producing the geminate radical ion pair with fluorescer radical cation in an electronically excited state and quencher radical anion in the ground state.

引用

页码：5070 / 5073

页数：4

共 25 条

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[9] A CRITICAL CONSIDERATION ON THE LACK OF INVERTED REGION IN THE REHM-WELLER PLOT FOR ELECTRON-TRANSFER FLUORESCENCE QUENCHING
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