SYNTHESIS OF RODLIKE DISTELLENES

被引：28

作者：

GLEITER, R

BORZYK, O

机构：

[1] Organisch-Chemisches Institut, Universität Heidelberg, D‐69120

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1995年 / 34卷 / 09期

关键词：

DISTELLENES; HYDROCARBONS; THROUGH-BOND INTERACTIONS;

D O I：

10.1002/anie.199510011

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An intramolecular Paterno–Büchi reaction and a McMurry coupling are key reactions in the synthesis of the new rodlike compounds 1 (X = CH2, O). The photoelectron spectra of 1 and 2 indicate that the stellane framework provides a good relay for through‐bond interactions between π bonds. (Figure Presented.) Copyright © 1995 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：1001 / 1003

页数：3

共 20 条

[1] INTERACTIONS BETWEEN NONCONJUGATED PI-SYSTEMS [J].

GLEITER, R ;

SCHAFER, W .

ACCOUNTS OF CHEMICAL RESEARCH, 1990, 23 (11) :369-375

[2] 4 6-DIMETHYLENETRICYCLO[3.3.0.03,7]OCTANE-2-ONE AND 2,4,6-TRIMETHYLENETRICYCLO[3.3.0.03,7]OCTANE [J].

GLEITER, R ;

SIGWART, C ;

KISSLER, B .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (11) :1525-1526

[3] THE BICYCLO[1.1.1]PENTANE FRAMEWORK - AN EXCELLENT RELAY FOR PI-SIGMA-CONJUGATION [J].

GLEITER, R ;

PFEIFER, KH ;

SZEIMIES, G ;

BUNZ, U .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (04) :413-415

[4] RELAY CONJUGATION VIA TWISTED 6-MEMBERED AND 7-MEMBERED RINGS [J].

GLEITER, R ;

KISSLER, B ;

GANTER, C .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1987, 26 (12) :1252-1253

[5]

Gleiter R., 1989, ANGEW CHEM, V101, P1561

[6]

GLEITER R, 1987, ANGEW CHEM, V99, P1292

[7]

Gleiter R., 1990, ANGEW CHEM, V102, P418

[8] THE SYNTHESIS OF 2,6-DIMETHYLENETRICYCLO[3.3.0.03,7]OCTANE [J].

KISSLER, B ;

GLEITER, R .

TETRAHEDRON LETTERS, 1985, 26 (02) :185-188

[9]

KISSLER B, 1987, TETRAHEDRON LETT, V28, P6151

[10]

MANCUSO AJ, 1981, SYNTHESIS-STUTTGART, P165

← 1 2 →