ELECTROPHILIC ADDITIONS TO 7-METHYLENENORBORNENES AND 7-ISOPROPYLIDENENORBORNENES - CAN REMOTE SUBSTITUENTS SWAMP ELECTROSTATIC CONTROL OF PI-FACE SELECTIVITY

被引：41

作者：

MEHTA, G

GUNASEKARAN, G

GADRE, SR

SHIRSAT, RN

GANGULY, B

CHANDRASEKHAR, J

机构：

[1] UNIV POONA,DEPT CHEM,POONA 411007,INDIA

[2] INDIAN INST SCI,DEPT ORGAN CHEM,BANGALORE 560012,KARNATAKA,INDIA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 08期

关键词：

D O I：

10.1021/jo00087a001

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

pi-Face selectivities in electrophilic additiions (typically CCl2) to 7-methylenenorbornenes and 7-isopropylidenenorbornenes are modulated by endo-substituents.

引用

页码：1953 / 1955

页数：3

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