MASS-TRANSPORT ENHANCEMENT BY RISING BUBBLE CURTAINS

被引:18
作者
SUTIJA, DP
TOBIAS, CW
机构
[1] LAWRENCE BERKELEY LAB,DIV CHEM SCI,BERKELEY,CA 94720
[2] UNIV CALIF BERKELEY,DEPT CHEM ENGN,BERKELEY,CA 94720
关键词
D O I
10.1149/1.2059128
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Mass-transport enhancement by rising single and multiple bubble streams was monitored on a vertical electrode incorporating a mosaic of 100 x 100 mum sensing elements. Limiting current measurements of the reduction of ferric to ferrous sulfate revealed the presence of two distinct mechanisms: surface renewal is effective within a swath of five bubble diameters, while macroscopic laminar flows induced by rising bubbles contribute weaker enhancement over a wider path. Enhancement caused by a sheath of multiple side-by-side bubble streams can be well represented by the linear superposition of the effect of single streams. Generally, at equivalent volumetric rates, small bubbles are more effective than larger ones in reducing mass-transfer resistance to the underlying surface.
引用
收藏
页码:2599 / 2607
页数:9
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