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ATOMIC FLUORESCENCE SPECTROSCOPY OF COBALT WITH A HIGH-INTENSITY HOLLOW-CATHODE LAMP AND A MICROWAVE-EXCITED ELECTRODELESS DISCHARGE TUBE AS SOURCES
被引:16
作者:
FLEET, B
LIBERTY, KV
WEST, TS
机构:
[1] Chemistry Department, Imperial College, London, England
关键词:
D O I:
10.1016/S0003-2670(01)95590-4
中图分类号:
O65 [分析化学];
学科分类号:
070302 ;
081704 ;
摘要:
The fluorescence of cobalt atoms in air-hydrogen, air-propane and air-acetylene flames is described. Resonance fluorescence is obtained at 240.73, 242.49 and 252.14 nm with a high-intensity hollow-cathode lamp or a microwave-excited electrodeless discliarge tube as source. Cobalt may be determined by E.D.T. excitation in the range 0.01-7.0 p.p.m. in aqueous solution with a detection limit of 0.005 p.p.m. at the 240.73 nm line. An oxidizing air-propane or air-hydrogen flame is best for atomic fluorescence measurements. © 1969.
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页码:205 / &
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