ORGANOMETALLIC TRANSITION METAL DERIVATIVES CONTAINING FLUORINE .3. REACTIONS OF PERFLUOROALKYLMETAL CARBONYL IODIDES OF IRON AND COBALT WITH OLIGOTERTIARY PHOSPHINES

被引:22
作者
KING, RB
KAPOOR, RN
HOUK, LW
机构
[1] Department of Chemistry, University of Georgia, Athens
来源
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1969年 / 31卷 / 07期
关键词
D O I
10.1016/0022-1902(69)90036-0
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reactions of the RfFe(CO)4I (Rf n-C3F7 and (CF3)2CF) derivatives with chelating ditertiary phosphines give the red to brown non-ionic derivatives RfFe(CO)2I(diphos). However, reactions of the C5H5Co(CO)RfI(Rfn-C3F7 and n-C7F15) derivatives with chelating ditertiary phosphines give the yellow iodide salts [C5H5Co(diphos)Rf]I which can be converted to the corresponding hexafluorophosphate salts by metathesis with NH4PF6. The potentially tridentate ligand CH3C[CH2P(C6H5)2]3 behaves as only a bidentate ligand in its reactions with RfFe(CO)4I and C5H5Co(CO)RfI derivatives. The new compounds RfFe(CO)4I and C5H5Co(CO)RfI (Rf (CF3)2CF and n-C7F15) are also described. © 1969.
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页码:2179 / &
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