STRUCTURE OF AN OXYGEN-CARRYING COBALT COMPLEX

被引：34

作者：

WANG, BC

SCHAEFER, WP

机构：

[1] A. A. Noyes Laboratory of Chemical Physics, California Institute of Technology, Pasadena

来源：

SCIENCE | 1969年 / 166卷 / 3911期

关键词：

D O I：

10.1126/science.166.3911.1404

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

Bis(3-fluorosalicylaldehyde) ethylenediimine cobalt(II), a reversible oxygen-carrying compound, has been crystallized as a tetramer with two oxygen molecules bound to the four cobalt atoms, each oxygen molecule bridging between two metal atoms. These dimers are further linked by two bonds between the oxygen atom of the salicylaldehyde and the cobalt atom. The oxygen-to-oxygen distance, 1.21 angstroms in molecular oxygen, has increased to 1.308(28) angstroms (where the number in parentheses is the estimated standard deviation) in this compound, the shortest distance yet observed in such a bridging arrangement.

引用

页码：1404 / &

共 17 条

[1]

BAYER E, 1967, STRUCT BOND, V2, P181

[2]

CALLIGARIS M, 1969, CHEM COMMUN, P763

[3] BINUCLEAR COMPLEX IONS .3. FORMATION OF PEROXO AND CYANO BRIDGED COMPLEXES BY OXIDATION OF PENTACYANO COMPLEX OF COBALT(II) [J].