BIS(CHLOROZINC)TETRACARBONYLIRON - PREPARATION, CHARACTERIZATION, AND METATHETICAL REACTIONS WITH ORGANOTIN CHLORIDES

被引：9

作者：

BURLITCH, JM

WINTERTON, RC

机构：

[1] Department of Chemistry, Cornell University, Ithaca

来源：

INORGANIC CHEMISTRY | 1979年 / 18卷 / 08期

关键词：

D O I：

10.1021/ic50198a053

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Derivatives of H2Fe(CO)4 are commonly made from neutral iron carbonyls1 or from Fe(CO)42-.2, 3 Vigorous conditions required for reaction of the former with organotin halides frequently give unpredictable products.1 Little is known about the metathetical reactions of zinc-to-transition-metal bonds or their use in synthetic intermediates. Previous work in our laboratory showed that Zn-Co and Zn-Mn bonds were cleaved efficiently by triorganotin chlorides.4 Herein we describe the synthesis of (ClZn)2 Fe(CO)4.C6H14O3 and its reactivity with organotin halides.5 Chlorozinc and bromozinc derivatives of some molybdenum complexes have been prepared and structurally characterized by Oliver and co-workers.6-9. © 1979, American Chemical Society. All rights reserved.

引用

收藏

页码：2309 / 2311

页数：3

相关论文

共 24 条

[1] CRYSTAL AND MOLECULAR STRUCTURE OF (BRHG)2FE(CO)4 [J].

BAIRD, HW ;

DAHL, LF .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1967, 7 (03) :503-+

[2]

BROOKS EH, 1970, ORGANOMET CHEM REV A, V6, P227

[3] Studies in the Chemistry of Bonds between Metals. I. The Synthesis of Transition Metal Carbonyl Derivatives of Zinc and Cadmium by a Metal-Exchange Reaction [J].

Burlitch, James M. ;

Ferrari, Alvaro .

INORGANIC CHEMISTRY, 1970, 9 (03) :563-569

[4] STUDIES IN CHEMISTRY OF BONDS BETWEEN METALS - TRANSITION-METAL CARBONYL DERIVATIVES OF THALLIUM [J].

BURLITCH, JM ;

THEYSON, TW .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1974, (08) :828-837

[5] REACTIONS OF PENTACARBONYLIRON WITH ORGANOTIN DERIVATIVES - FORMATION OF BIS(DIORGANOTIN-TETRACARBONYLIRON) COMPLEXES [J].

BURNHAM, RA ;

LYLE, MA ;

STOBART, SR .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1977, 125 (02) :179-183

[6] CHEMISTRY OF POLYNUCLEAR COMPOUNDS .X. INTERACTION OF COMPOUNDS FE(CO)4(HGY)2 (WHERE Y = CL OR BR) WITH HALIDE IONS (X-) AND WITH AMINES [J].

CHALMERS, AA ;

LEWIS, J ;

WILD, SB .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1968, (05) :1013-+

[7] DISODIUM TETRACARBONYLFERRATE - TRANSITION-METAL ANALOG OF A GRIGNARD-REAGENT [J].

COLLMAN, JP .

ACCOUNTS OF CHEMICAL RESEARCH, 1975, 8 (10) :342-347

[8] CHEMISTRY OF METAL CARBONYLS .39. ORGANOTIN(CARBONYL)-IRON COMPLEXES [J].

COTTON, JD ;

KNOX, SAR ;

PAUL, I ;

STONE, FGA .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1967, (02) :264-&

[9] STUDIES ON MAIN-GROUP METAL-TRANSITION METAL BONDED COMPOUNDS .5. STRUCTURE OF (ETA5-C5H5)2MOH2.ZNBR2.DMF [J].

CROTTY, DE ;

ANDERSON, TJ ;

GLICK, MD ;

OLIVER, JP .

INORGANIC CHEMISTRY, 1977, 16 (09) :2346-2350

[10] STUDIES ON MAIN GROUP METAL-TRANSITION METAL BONDED COMPOUNDS .3. SYNTHESIS AND STRUCTURE OF ETA-C5H5(CO)3MOZNBR.2THF AND [(C4H9)4N][ETA-C5H5(CO)3MO] [J].

CROTTY, DE ;

COREY, ER ;

ANDERSON, TJ ;

GLICK, MD ;

OLIVER, JP .

INORGANIC CHEMISTRY, 1977, 16 (04) :920-924