ISOCYANATES FROM PRIMARY AMINES AND CARBON-DIOXIDE - DEHYDRATION OF CARBAMATE ANIONS

被引：63

作者：

WALDMAN, TE ^{[1
]}

MCGHEE, WD ^{[1
]}

机构：

[1] MONSANTO CO,ST LOUIS,MO 63167

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 08期

关键词：

D O I：

10.1039/c39940000957

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Carbamate anions, derived from primary amines CO2 and an added base (eg. NEt(3)), undergo rapid reaction with electrophilic 'dehydrating agents' (e.g. POCl3, P4O10) to give the corresponding isocyanates in excellent yields.

引用

页码：957 / 958

页数：2

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