A ROUTE TO VICINAL DIAMINES FROM THE SAMARIUM(II) IODIDE-MEDIATED COUPLING OF ALDIMINES

被引：91

作者：

ENHOLM, EJ

FORBES, DC

HOLUB, DP

机构：

[1] Department of Chemistry, University of Florida, Gainesville, Florida

来源：

SYNTHETIC COMMUNICATIONS | 1990年 / 20卷 / 07期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1080/00397919008052801

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new method to construct vicinal diamines from aldimines mediated by the one electron reductant, samarium diiodide is described. The reaction probably involves a ketyl-like radical coupling mechanism. © 1990, Taylor & Francis Group, LLC. All rights reserved.

引用

收藏

页码：981 / 987

页数：7

相关论文

共 32 条

[1]

BALYKOVA IA, 1975, TR PERM S KH INT, V112, P26

[2] SCOPE AND LIMITATIONS OF THE REDUCTIVE COUPLING OF AROMATIC ALDIMINE DERIVATIVES WITH FORMATION OF 1,2-DIARYLETHYLENEDIAMINE UNITS, USING LOW-VALENT TITANIUM REAGENTS [J].

BETSCHART, C ;

SCHMIDT, B ;

SEEBACH, D .

HELVETICA CHIMICA ACTA, 1988, 71 (08) :1999-2021

[3]

EHNOLM E, 1989, J ORG CHEM, V54, P5841

[4] SAMARIUM(II) IODIDE MEDIATED TRANSFORMATION OF CARBOHYDRATES TO CARBOCYCLES [J].

ENHOLM, EJ ;

TRIVELLAS, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (16) :6463-6465

[5]

ENHOLM EJ, 1989, TETRAHEDRON LETT, P1063

[6] A SAMARIUM(II) IODIDE PROMOTED TANDEM RADICAL CYCLIZATION - THE TOTAL SYNTHESIS OF (+/-)-HYPNOPHILIN AND THE FORMAL SYNTHESIS OF (+/-)-CORIOLIN [J].

FEVIG, TL ;

ELLIOTT, RL ;

CURRAN, DP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (15) :5064-5067

[7] SAMARIUM(II) DI-IODIDE INDUCED REDUCTIVE COUPLING OF ALPHA,BETA-UNSATURATED ESTERS WITH CARBONYL-COMPOUNDS LEADING TO A FACILE SYNTHESIS OF GAMMA-LACTONE [J].

FUKUZAWA, S ;

NAKANISHI, A ;

FUJINAMI, T ;

SAKAI, S .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1988, (07) :1669-1675

[8] INTRAMOLECULAR REDUCTIVE CYCLIZATION OF UNSATURATED KETO-ESTERS OR ALDO-ESTERS BY SAMARIUM(II) DIIODIDE - A READY SYNTHESIS OF BICYCLIC GAMMA-LACTONES [J].

FUKUZAWA, S ;

IIDA, M ;

NAKANISHI, A ;

FUJINAMI, T ;

SAKAI, S .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1987, (12) :920-921

[9] CHEMICAL AND BIOLOGICAL PROPERTIES OF A NEW SERIES OF CIS-DIAMMINEPLATINUM(II) ANTITUMOR AGENTS CONTAINING 3 NITROGEN DONORS - CIS-[PT(NH3)2(N-DONOR)CL]+ [J].

HOLLIS, LS ;

AMUNDSEN, AR ;

STERN, EW .

JOURNAL OF MEDICINAL CHEMISTRY, 1989, 32 (01) :128-136

[10]

HORNER L, 1970, TETRAHEDRON LETT, P1103

← 1 2 3 4 →