On phase separation in the TiO2-SnO2 system

被引:20
作者
Gupta, P. K. [1 ]
Cooper, A. R. [1 ]
机构
[1] Case Western Reserve Univ, Div Met & Mat Sci, Cleveland, OH 44106 USA
关键词
D O I
10.1080/14786437008238443
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Following a procedure developed by Swanger, Gupta and Cooper (1970). a computer simulation of the kinetics of spinodal decomposition of a binary solution is compared with recent experimental results on the decomposition of the solid solution containing 0.6 mole fraction SnO2 and 0.4 mole fraction TiO2. Only one adjustable parameter, namely concentration conductivity, kT<(M) over dot>, is required for comparison. The calculations agree approximately with the thickness measurements of the two phases over the entire time span studies, if a value of kT<(M) over dot> = 10(-16) cm(2)/sec at 1000 degrees C is chosen, suggesting that the decomposition of SnO2-TiO2 follows a spinodal mechanism.
引用
收藏
页码:611 / 616
页数:6
相关论文
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