A QUANTITATIVE STUDY OF AL-27 MAS NMR IN CRYSTALLINE YAG

被引：334

作者：

MASSIOT, D

BESSADA, C

COUTURES, JP

TAULELLE, F

机构：

[1] CRPHT-CNRS

来源：

JOURNAL OF MAGNETIC RESONANCE | 1990年 / 90卷 / 02期

关键词：

D O I：

10.1016/0022-2364(90)90130-2

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

A quantitative 27Al NMR analysis of yttrium aluminum garnet. involving a complete computation of the quadrupolar interaction in MAS conditions, has been performed. Results show a very good agreement with the known X-ray structure: three tetrahedral aluminum sites and two octahedral. This analysis provides a new approach for obtaining quantitative results from MAS NMR spectra of quadrupolar nuclei in different environments. © 1990.

引用

收藏

页码：231 / 242

页数：12

相关论文

共 27 条

[1] METHODS FOR ANALYZING SPECTROSCOPIC LINE-SHAPES - NMR SOLID POWDER PATTERNS [J].

ALDERMAN, DW ;

SOLUM, MS ;

GRANT, DM .

JOURNAL OF CHEMICAL PHYSICS, 1986, 84 (07) :3717-3725

[2] AL-27 NMR-STUDY OF ALPO4-21 AND ANDALUSITE - ADVANTAGES OF HIGH-FIELD AND VERY FAST MAS [J].

ALEMANY, LB ;

TIMKEN, HKC ;

JOHNSON, ID .

JOURNAL OF MAGNETIC RESONANCE, 1988, 80 (03) :427-438

[3] THE 2ND ORDER INFLUENCE OF THE NUCLEAR-QUADRUPOLE INTERACTION ON THE CENTRAL LINE IN THE NMR OF QUADRUPOLAR NUCLEI USING RAPID SAMPLE SPINNING [J].

BEHRENS, HJ ;

SCHNABEL, B .

PHYSICA B & C, 1982, 114 (02) :185-190

[4]

BERTAUT F, 1956, CR HEBD ACAD SCI, V242, P382

[5] 27AL AND 89Y NUCLEAR MAGNETIC RESONANCE IN YTTRIUM-ALUMINUM GARNET [J].

BROG, KC ;

JONES, WH ;

VERBER, CM .

PHYSICS LETTERS, 1966, 20 (03) :258-&

[6] THE POLYACRYLAMIDE-GEL - A NOVEL ROUTE TO CERAMIC AND GLASSY OXIDE POWDERS [J].

DOUY, A ;

ODIER, P .

MATERIALS RESEARCH BULLETIN, 1989, 24 (09) :1119-1126

[7]

DOUY A, Patent No. 8803370

[8] STRUCTURAL CHARACTERIZATION OF CERAMIC PHASES WITH HIGH-RESOLUTION AL-27 NMR [J].

DUPREE, R ;

LEWIS, MH ;

SMITH, ME .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1988, 21 :109-116

[9]

FENZKE D, 1984, CHEM PHYS LETT, V111, P171, DOI 10.1016/0009-2614(84)80458-3

[10] NMR LINE SHIFTS CAUSED BY THE 2ND-ORDER QUADRUPOLAR INTERACTION [J].

FREUDE, D ;

HAASE, J ;

KLINOWSKI, J ;

CARPENTER, TA ;

RONIKIER, G .

CHEMICAL PHYSICS LETTERS, 1985, 119 (04) :365-367