UNSYMMETRIC DICOPPER(II) COMPLEXES OF DINUCLEATING LIGANDS BEARING CHEMICALLY DISTINCT COORDINATION ENVIRONMENTS

被引:98
作者
CRANE, JD
FENTON, DE
LATOUR, JM
SMITH, AJ
机构
[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND
[2] CEN,DEPT RECH FONDAMENTALE,CHIM LAB,UA 1194,F-38041 GRENOBLE,FRANCE
来源
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1991年 / 11期
关键词
D O I
10.1039/dt9910002979
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Dicopper(II) complexes of unsymmetrical dinucleating Schiff-base ligands bearing chemically distinct co-ordination sites have been prepared and their properties studied. The ligands were derived from the condensation of 4-bromo-2-formyl-6-(4-methylpiperazin-1-ylmethyl)phenol and 4-bromo-2-[(2-diethylaminoethyl)ethylaminomethyl]-6-formylphenol with 2-(aminomethyl)pyridine, 2-(2-aminoethyl)pyridine, and 2-(aminomethyl)-4-nitrophenol.
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页码:2979 / 2987
页数:9
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