CATALYTIC CONVERSION OF CCL2F2 ON A GAMMA-AL2O3 CATALYST

被引：25

作者：

BELL, TN ^{[1
]}

KIRSZENSZTEJN, P ^{[1
]}

CZAJKA, B ^{[1
]}

机构：

[1] ADAM MICKIEWICZ UNIV POZNAN,FAC CHEM,PL-60780 POZNAN,POLAND

来源：

CATALYSIS LETTERS | 1995年 / 30卷 / 1-4期

关键词：

CFCS; CATALYTIC HYDROGENOLYSIS; ALUMINA;

D O I：

10.1007/BF00813697

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Reaction of hydrogen with CCl2F2 has been studied on a gamma-Al2O3 catalyst at 300 degrees C. Pure gamma-Al2O3 appears to be unselective in the catalytic conversion of CCl2F2, however, halogenated alumina showed high activity in a reaction leading to the formation of disproportionation products.

引用

页码：305 / 312

页数：8

共 14 条

[1] THE CHEMICAL-STATE OF TIN IN PLATINUM TIN ALUMINA CATALYSTS [J].

ADKINS, SR ;

DAVIS, BH .

JOURNAL OF CATALYSIS, 1984, 89 (02) :371-379

[2]

AHMED M, 1993, SEP P INT C OZ DEPL

[3]

BUCKMAN WR, 1972, Patent No. 3644545

[4] HYDROGENOLYSIS OF DICHLOROTETRAFLUOROETHANE ISOMERIC MIXTURES FOR THE FORMATION OF 1.1.1.2 - TETRAFLUOROETHANE [J].

GERVASUTTI, C ;

MARANGONI, L ;

MARRA, W .

JOURNAL OF FLUORINE CHEMISTRY, 1981, 19 (01) :1-20

[5]

Kellner C. S., 1989, Hydrodehalogenation of CF3CHClF in the Presence of Supported Pd, Patent No. [US 4,873,381, 4873381]

[6] STRUCTURE AND ACTIVITY OF FLUORINATED ALUMINA .2. NATURE OF THE ACTIVE-SITE FOR 2-METHYLPROPENE OLIGOMERIZATION [J].

KERKHOF, FPJM ;

OUDEJANS, JC ;

MOULIJN, JA ;

MATULEWICZ, ERA .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 1980, 77 (01) :120-130

[7] EFFECT OF HYDROGEN TREATMENT ON THE POROUS STRUCTURE OF AL2O3-SNO2 SYSTEM [J].

KIRSZENSZTEJN, P ;

BELL, TN .

CATALYSIS LETTERS, 1993, 21 (3-4) :371-380

[8]

KIRSZENSZTEJN P, 1993, CATAL LETT, V18, P319

[9]

KOWALAK S, 1981, ACTA CHIM HUNG, V107, P19

[10]

MANZER LE, 1993, ADV CATAL, V39

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