SYNTHESIS AND NEUTRON-DIFFRACTION STUDY OF NA3WN3 AND NA3MON3

被引：25

作者：

RAUCH, PE

DISALVO, FJ

BRESE, NE

PARTIN, DE

OKEEFE, M

机构：

[1] CORNELL UNIV,DEPT CHEM,ITHACA,NY 14853

[2] ARIZONA STATE UNIV,DEPT CHEM,TEMPE,AZ 85287

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1994年 / 110卷 / 01期

关键词：

D O I：

10.1006/jssc.1994.1151

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We have used our ambient pressure method for the synthesis of ternary alkali metal nitrides to synthesize a new class of nitrides, Na3MN3 (M = Mo or W). These compounds were synthesized from the metal nitride and NaNH2 at 500-degrees-C under flowing ammonia at atmospheric pressure. The structures were examined using X-ray powder diffraction and neutron powder diffraction and were found to be identical with that obtained from the single crystal prepared at high pressure by Ostermann, Zachwieja, and Jacobs. (C) 1994 Academic Press, Inc.

引用

页码：162 / 166

页数：5

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