SYNTHESIS AND CHARACTERIZATION OF LINKED TRIOSMIUM CLUSTERS USING THE BIS(DIPHENYLPHOSPHINO)ACETYLENE LIGAND

被引：17

作者：

JOHNSON, BFG ^{[1
]}

LEWIS, J ^{[1
]}

MASSEY, AD ^{[1
]}

RAITHBY, PR ^{[1
]}

WONG, WT ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,CHEM LAB,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 397卷 / 02期

关键词：

D O I：

10.1016/0022-328X(90)80247-W

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Os3(CO)11(NCMe) with bis(diphenylphosphino)acetylene (dppa) at room temperature affords [Os3(CO)11]2(dppa) (1) in good yield, while Os3(CO)10(NCMe)2 with an excess of dppa gives [Os3(CO)10(dppa)]3 (2) and [Os3(CO)10(dppa)]4 (3) in moderate yields. The structure of 1 has been determined by a single crystal X-ray diffraction study. © 1990.

引用

页码：C28 / C30

页数：3

共 3 条

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