CRYSTAL-STRUCTURE OF [RH2(MU(2)-O2CME)2(MU(2)-(CH2)PPH2)(MU(2)-(C6H4)PPH2).PPH3].2CH2CL2, A COMPOUND WITH A DIPHENYLPHOSPHINOMETHANIDE GROUP IN A BRIDGING (P,C) COORDINATION

被引：10

作者：

BORRACHERO, MV

ESTEVAN, F

GARCIAGRANDA, S

LAHUERTA, P

LATORRE, J

PERIS, E

SANAU, M

机构：

[1] UNIV OVIEDO,DEPT QUIM FIS & ANAL,E-33006 OVIEDO,SPAIN

[2] UNIV VALENCIA,DEPT QUIM INORGAN,E-46100 BURJASSOT,SPAIN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 24期

关键词：

D O I：

10.1039/c39930001864

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of the monometallated compound [Rh2(mu2-O2CMe)3 {mu2-(C6H4)PMePh}.(HO2CMe)2] and two moles of PPh3 yields [Rh2(mu2-O2CMe)2{mu2-CH2PPh2}{mu2-(C6H4)PPh2}PPh3].2CH2Cl2 which according to the crystal structure contains an orthometallated triphenylphosphine and a diphenylphosphinomethanide group bridging the two rhodium atoms.

引用

收藏

页码：1864 / 1865

页数：2

相关论文

共 15 条

[1] ORTHOMETALLATION REACTION IN DIRHODIUM(II) COMPOUNDS - SELECTIVE FORMATION OF DOUBLY-METALATED COMPOUNDS WITH HEAD-TO-HEAD STRUCTURE [J].

BORRACHERO, MV ;

ESTEVAN, F ;

LAHUERTA, P ;

PAYA, J ;

PERIS, E .

POLYHEDRON, 1993, 12 (13) :1715-1717

[2] PREPARATION AND X-RAY CRYSTAL-STRUCTURE OF [PT2(PPH3)2(MU-PH2PCHPPH2)(MU-PH2PCH2PPH2)][PF6], A DIPLATINUM(I) COMPLEX CONTAINING THE BIS(DIPHENYLPHOSPHINO)METHANIDE LIGAND IN A NOVEL BRIDGING ROLE [J].

BROWN, MP ;

YAVARI, A ;

MANOJLOVICMUIR, L ;

MUIR, KW .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 256 (01) :C19-C22

[3] STRUCTURAL AND ELECTROCHEMICAL CHARACTERIZATION OF THE NOVEL ORTHO-METALATED DIRHODIUM(II) COMPOUNDS RH2(O2CCH3)2[(C6H5)2P(C6H4)]2.2L [J].

CHAKRAVARTY, AR ;

COTTON, FA ;

TOCHER, DA ;

TOCHER, JH .

ORGANOMETALLICS, 1985, 4 (01) :8-13

[4] (DIPHENYLPHOSPHINO)METHYL COMPLEXES OF TITANIUM AND ZIRCONIUM - SYNTHESIS AND CHARACTERIZATION - MOLECULAR-STRUCTURE OF CPCP-STAR-TI(CH2PPH2)2 (CP = C5H5, CP-STAR = C5ME5) [J].

CUENCA, T ;

FLORES, JC ;

ROYO, P ;

LARSONNEUR, AM ;

CHOUKROUN, R ;

DAHAN, F .

ORGANOMETALLICS, 1992, 11 (02) :777-780

[5] METALLVERBINDUNGEN YLIDEN .6. SYNTHESIS AND PROPERTIES OF TRANS-DIMETHYLBIS(TRIMETHYLPHOSPHINE)COBALT(III)-[DIMETHYLPHOSPHONIUM-BIS(METHYLIDE)] [J].

KARSCH, HH ;

KLEIN, HF ;

KREITER, CG ;

SCHMIDBA.H .

CHEMISCHE BERICHTE-RECUEIL, 1974, 107 (11) :3692-3696

[6] FUNCTIONAL DERIVATIVES OF TRIMETHYLPHOSPHINE .6. "LITHIUM-DIMETHYLPHOSPHINOMETHANIDE, (CH3)2PCH2LI, TETRAORGANODIPHOSPHINOMETHANES, R2PCH2P(CH3)2, AND TRIS(DIMETHYLPHOSPHINOMETHYL)PHOSPHINE, P[CH2P(CH3)2]3 [J].

KARSCH, HH ;

SCHMIDBAUR, H .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1977, 32 (07) :762-767

[7] EXCHANGE-REACTION OF BRIDGING ACETATE LIGANDS AND REVERSIBLE ELECTROPHILIC RHODIUM-CARBON ACTIVATION IN ORTHO-METALATED RHODIUM(II) COMPOUNDS WITH ACETIC-ACID - KINETIC-STUDY OF THE EXCHANGE-REACTION OF ACETATES WITH CD3CO2D IN THE COMPOUND RH2(O2CCH3)3[(C6H4)P(C6H5)2].2HO2CCH3 [J].

LAHUERTA, P ;

PERIS, E .

INORGANIC CHEMISTRY, 1992, 31 (22) :4547-4551

[8] REACTIONS OF DIRHODIUM(II) MONOMETALATED COMPOUNDS WITH PHOSPHINES - FACTORS AFFECTING THE REACTIVITY AND THE STRUCTURE OF THE DOUBLY-METALATED COMPOUNDS - MOLECULAR-STRUCTURE OF RH2(O2CCH3)2[(C6H4)P(C6H5)2][(P-CLC6H3)P(P-CLC6H4)2]BULLET(HO2CCH3)2-BULLET-1/2(C6H6), A COMPOUND WITH 2 DIFFERENT METALATED PHOSPHINES [J].

LAHUERTA, P ;

PAYA, J ;

PERIS, E ;

AGUIRRE, A ;

GARCIAGRANDA, S ;

GOMEZBELTRAN, F .

INORGANICA CHIMICA ACTA, 1992, 192 (01) :43-49

[9]

LAHUERTA P, 1990, INORG CHIM ACTA, V205, P91

[10]

LAHUERTA P, IN PRESS J CHEM SOC