IMPROVED SYNTHESIS OF 5,11,17,23,29-PENTA-T-BUTYLCALIX[5]ARENE-31,32,33,34,35-PENTOL AND IMMOBILIZATION OF THE CONFORMATION BY O-ALKYLATION

被引：22

作者：

IWAMOTO, K ^{[1
]}

ARAKI, K ^{[1
]}

SHINKAI, S ^{[1
]}

机构：

[1] KYUSHU UNIV, FAC ENGN, DEPT ORGAN SYNTH, FUKUOKA 812, JAPAN

来源：

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1994年 / 67卷 / 05期

关键词：

D O I：

10.1246/bcsj.67.1499

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthetic method of the title compound was improved to 16.1% yield. The H-1 NMR studies established that the oxygen-through-the-annulus rotation is not inhibited by the butyl group but inhibited by the bulkier octyl group.

引用

页码：1499 / 1502

页数：4

共 8 条

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[2]

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[4]

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[5]

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[6]

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[7]

NINAGAWA A, 1982, MAKROMOL CHEM-RAPID, V3, P65

[8] MOLECULAR DESIGN OF CALIXARENE-BASED URANOPHILES WHICH EXHIBIT REMARKABLY HIGH-STABILITY AND SELECTIVITY [J].

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