REARRANGEMENTS AMONG GAS-PHASE IONS OF C8H8 ISOMERS - PHOTODISSOCIATION-SPECTROSCOPIC INVESTIGATION

被引：18

作者：

DUNBAR, RC ^{[1
]}

KIM, MS ^{[1
]}

OLAH, GA ^{[1
]}

机构：

[1] UNIV SO CALIF,DEPT CHEM,LOS ANGELES,CA 90007

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1979年 / 101卷 / 06期

关键词：

D O I：

10.1021/ja00500a002

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photodissociation spectroscopy is used to explore the structures of the C8H8+ and C8H9+ ions obtained in gas phase from styrene, cyclooctatetraene, and barrelene. The C8H8+ ions do not interconvert on a time scale of seconds, and the parentions of styrene and barrelene appear to retain the neutral structure, while the structure of the COT parent ion is uncertain. The C8H9+ ions obtained by H3O+ protonation all have the same spectrum, and are assigned as having the styryl ion structure. © 1979, American Chemical Society. All rights reserved.

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页码：1368 / 1370

页数：3

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