NUCLEAR-MAGNETIC-RESONANCE SPECTRAL STUDY OF 2-ACETYLPYRIDINE N-4-ALKYLTHIOSEMICARBAZONES AND THEIR COBALT(III) COMPLEXES

被引：67

作者：

WEST, DX

MOKIJEWSKI, BL

GEBREMEDHIN, H

ROMACK, TJ

机构：

[1] Department of Chemistry, Illinois State University, Normal, IL

来源：

TRANSITION METAL CHEMISTRY | 1992年 / 17卷 / 05期

关键词：

D O I：

10.1007/BF02910713

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

H-1 and C-13 n.m.r. spectra are reported for a series of 2-acetylpyridine 4N-alkylthiosemicarbazones in order to study the effect of increased size of the alkyl function on the ratio of isomers present in solution. Similarly, n.m.r. data for the bis(thiosemicarbazone)cobalt(III) complexes are included, as well as these complexes' ligand field parameters.

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页码：384 / 386

页数：3

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