EXTENDED TRICYCLIC TERPANES IN SEDIMENTS AND PETROLEUMS

被引:140
作者
DEGRANDE, SMB [1 ]
NETO, FRA [1 ]
MELLO, MR [1 ]
机构
[1] CENPES,PETROBRAS,BR-21949 RIO JANEIRO,BRAZIL
关键词
EXTENDED TRICYCLIC TERPANES; TANDEM MASS SPECTROMETRY; DEPOSITIONAL ENVIRONMENTS;
D O I
10.1016/0146-6380(93)90112-O
中图分类号
P3 [地球物理学]; P59 [地球化学];
学科分类号
0708 ; 070902 ;
摘要
An extended series of tricyclic terpanes was identified in sediments and petroleums from Brazil. The identification of the tricyclic terpanes was based on their chromatographic behavior and characteristic MS/MS transitions from molecular ions to m/z 191. We identified tricyclic terpane homologs up to C54. The presence of this extended series, from C19 up to C54, varies considerably with depositional environment, being prominent in saline lacustrine and marine carbonate settings. This suggests that the biological precursor organism lived in moderate conditions of salinity.
引用
收藏
页码:1039 / 1047
页数:9
相关论文
共 31 条
[1]   CYCLOALKANE CONSTITUENTS OF BITUMEN FROM GREEN RIVER SHALE [J].
ANDERS, DE ;
ROBINSON, WE .
GEOCHIMICA ET COSMOCHIMICA ACTA, 1971, 35 (07) :661-&
[2]  
Aquino Neto F.R., 1983, ADV ORG GEOCHEM, P659
[3]   NOVEL SERIES OF TRICYCLIC AROMATIC TERPANES CHARACTERIZED IN TASMANIAN TASMANITE [J].
AZEVEDO, DA ;
NETO, FRA ;
SIMONEIT, BRT ;
PINTO, AC .
ORGANIC GEOCHEMISTRY, 1992, 18 (01) :9-16
[4]  
AZEVEDO DD, 1990, ORG MASS SPECTROM, V25, P475
[5]  
BERTANI RT, 1985, J PETROL GEOL, V8, P199
[6]   LAGOA FEIA FORMATION (LOWER CRETACEOUS), CAMPOS BASIN, OFFSHORE BRAZIL - RIFT-VALLEY STAGELACUSTRINE CARBONATE RESERVOIRS .1. [J].
BERTANI, RT ;
CAROZZI, AV .
JOURNAL OF PETROLEUM GEOLOGY, 1985, 8 (01) :37-58
[7]   BIOLOGICAL MARKER COMPOUNDS AS INDICATORS OF THE DEPOSITIONAL HISTORY OF THE MAOMING OIL-SHALE [J].
BRASSELL, SC ;
EGLINTON, G ;
FU, JM .
ORGANIC GEOCHEMISTRY, 1986, 10 (4-6) :927-941
[8]  
CONNAN J, 1987, 13TH INT M ORG GEOCH, P89
[9]  
DEGRANDE SMB, 1992, THESIS U FEDERAL RIO
[10]  
EKEWOZOR CM, 1982, TETRAHEDRON LETT, V23, P2711