SHORT SYNTHESIS OF 1,3Z,6Z,9Z-TETRAENE HYDROCARBONS - LEPIDOPTERAN SEX ATTRACTANTS

被引：27

作者：

MILLAR, JG

UNDERHILL, EW

机构：

[1] National Research Council, Plant Biotechnology Institute, 110 Gymnasium Road, Saskatoon,SK,S7N OW9, Canada

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1986年 / 64卷 / 12期

关键词：

D O I：

10.1139/v86-402

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A short, convergent synthesis of 1,3Z,6Z,9Z-tetraene hydrocarbons was developed. A key step was the regioselective alkylation of 1,s-dibromo-2-pentyne. The method was used to synthesize tetraenes of chain lengths CI8-C2, to be used in field trials as sex attractants and (or) inhibitors of the winter moth, Operophtera brumata L., and the Bruce spanworm 0. bruceata H. (Lepidoptera: Geometridae).

引用

页码：2427 / 2430

页数：4

共 17 条

[1]

BAKER R, 1984, J CHEM RES, V5, P190

[2]

BESTMANN HJ, 1982, TETRAHEDRON LETT, V23, P4077

[3]

BRANDSMA L, 1971, PREPARATIVE ACETYLEN, P31

[4]

BROWN C. E., 1962, CANADIAN ENTOMOL, V94, P1103