METAL-AMMONIA REDUCTION OF SOME ACYL PHENOLS

被引：4

作者：

BIRCH, AJ

RAO, GSR

机构：

[1] Department of Chemistry, University of Manchester, Manchester

[2] Research School of Chemistry, Australian National University, Canberra, ACT

来源：

AUSTRALIAN JOURNAL OF CHEMISTRY | 1969年 / 22卷 / 04期

关键词：

D O I：

10.1071/CH9690761

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

2- and 4-Hydroxyacetophenone on reduction with metal-ammonia solutions give mainly pinacols with some of the alcohol; 3-hydroxyacetophenone gives no pinacol. In no case is hydrogenolysis of the side-chain oxygen observed. 4-Hydroxy-propiophenone gives a good yield of a mixture of stereoisomeric pinacols related to hexoestrol. © 1969, CSIRO. All rights reserved.

引用

页码：761 / &

共 12 条

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