ELECTROCHEMICAL CHARACTERIZATION OF ((ETA5-C5H5)2VCO)- ANION AND ELECTROCHEMICAL BEHAVIOR OF (ETA5-C5H5)2VCO AND ETA5-C5H5V(CO)4

被引：17

作者：

ELMURR, N

MOISE, C

RIVECCIE, M

TIROUFLET, J

机构：

[1] Laboratoire de Polarographie Organique (LA 33 associé au CNRS), Faculté des Sciences Gabriel, 21100 Dijon

来源：

INORGANICA CHIMICA ACTA | 1979年 / 32卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)91659-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

With the purpose of synthesizing chiral vanodium- (111) complexes of general formula η5-Cpη5 -Cp′V(CO)R an electrochemical approach has been made to obtain the ((η5-C5H5)2VCO)- anion. This arion can be generated from the corresponding neutral complex in a one electron reversible process, but it is unstable. A study of electrochemical behaviour of (η5 -C5H5)2 VCO under CO atmosphere and of η5 -C5- Hs V(CO)4 is presented to determine a possible path- way during the ECE decomposition process of the neutral carbonyl dicyclopentadienyl vanadium complex. © 1979.

引用

页码：189 / 192

页数：4

共 11 条

[1] CARBONYL-COMPLEXES OF BIS(CYCLOPENTADIENYL)VANADIUM(II) AND BIS(CYCLOPENTADIENYL)VANADIUM(III) - BIS(CYCLOPENTADIENYL)IODOVANADIUM(III), A MODEL COMPOUND FOR QUANTITATIVE ASSESSMENT OF REVERSIBLE CARBON-MONOXIDE COORDINATIVE ADDITION [J].