VIBRATIONAL-SPECTRA OF X2O7(N-) ANIONS

被引：11

作者：

ABBAS, MH

DAVIDSON, G

机构：

[1] Department of Chemistry, University of Nottingham, Nottingham, NG7 2RD, University Park

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 1994年 / 50卷 / 06期

关键词：

D O I：

10.1016/0584-8539(94)80037-5

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

A careful study of the Raman spectra of aqueous solutions containing X2O7n- anions, where X = P, n = 4; X = Cr or Se, n = 2, has shown for the first time that in all cases the deltaX-O-X bending mode occurs below 100 cm-1. In addition, further information on the XO3 terminal stretches was from FTIR spectra of the aqueous solutions. Consequently, more realistic vibrational assignments were obtained for these frequently-studied inorganic anions.

引用

页码：1153 / 1159

页数：7

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