OXYCHLORINE IONS IN INDUCTIVELY-COUPLED PLASMA-MASS SPECTROMETRY - EFFECT OF CHLORINE SPECIATION AS CL- AND CLO4-

被引：17

作者：

LONGERICH, HP ^{[1
]}

机构：

[1] MEM UNIV NEWFOUNDLAND,CTR EARTH RESOURCES RES,ST JOHNS A1B 3X5,NEWFOUNDLAND,CANADA

来源：

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY | 1993年 / 8卷 / 03期

关键词：

INDUCTIVELY COUPLED PLASMA MASS SPECTROMETRY; POLYATOMIC ION; CHLORINE; ALKALINE EARTH METAL; ROCKS;

D O I：

10.1039/ja9930800439

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Differences in the inductively coupled plasma mass spectra of 0.2 mol l-1 HCI and 0.2 mol l-1 HClO4 are reported. An enhancement was observed of the ion signal in the mass spectra of several oxychlorine species (ClO2+, HClO2+, ClO3+, HClO3+, HClO4+ and H2ClO4+) in a solution of HClO4 compared with the spectra of an equimolar solution of HCl. Spectra of Ca in HClO4 showed enhanced formation of CaClO+, CaClO2+, CaClO3+ and CaClO4+ compared with equimolar solutions of Ca in HCl. Similarly, solutions of Mg in HClO4 showed enhanced formation of MgClO2+, MgClO3+ and MgClO4+ compared with equimolar solutions of Mg in HCl. Other major rock-forming elements (Na, Al, K, Sc, Ti, Mn and Fe) did not produce enhanced signals from oxychlorine polyatomic ions.

引用

页码：439 / 444

页数：6

共 12 条

[1] STUDY OF THE EFFECTS OF CONCOMITANT ELEMENTS IN INDUCTIVELY COUPLED PLASMA MASS-SPECTROMETRY [J].

BEAUCHEMIN, D ;

MCLAREN, JW ;

BERMAN, SS .

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 1987, 42 (03) :467-490

[2] THE EFFECT OF PLASMA OPERATING PARAMETERS ON ANALYTE SIGNALS IN INDUCTIVELY COUPLED PLASMA-MASS SPECTROMETRY [J].

HORLICK, G ;

TAN, SH ;

VAUGHAN, MA ;

ROSE, CA .

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 1985, 40 (10-12) :1555-1572

[3] ICP-MS - A POWERFUL TOOL FOR HIGH-PRECISION TRACE-ELEMENT ANALYSIS IN EARTH SCIENCES - EVIDENCE FROM ANALYSIS OF SELECTED USGS REFERENCE SAMPLES [J].

JENNER, GA ;

LONGERICH, HP ;

JACKSON, SE ;

FRYER, BJ .

CHEMICAL GEOLOGY, 1990, 83 (1-2) :133-148

[4] DETERMINATION OF THE RARE-EARTH ELEMENTS IN GEOLOGICAL-MATERIALS BY INDUCTIVELY COUPLED PLASMA MASS-SPECTROMETRY [J].

LICHTE, FE ;

MEIER, AL ;

CROCK, JG .

ANALYTICAL CHEMISTRY, 1987, 59 (08) :1150-1157

[5] MASS-SPECTROMETRIC DETERMINATION OF THE TEMPERATURE OF AN ARGON INDUCTIVELY COUPLED PLASMA FROM THE FORMATION OF THE SINGLY CHARGED MONOXIDE RARE-EARTHS AND THEIR KNOWN DISSOCIATION-ENERGIES [J].

LONGERICH, HP .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1989, 4 (06) :491-497

[6] EFFECTS OF OPERATING-CONDITIONS ON THE DETERMINATION OF THE RARE-EARTH ELEMENTS BY INDUCTIVELY COUPLED PLASMA-MASS SPECTROMETRY (ICP-MS) [J].

LONGERICH, HP ;

FRYER, BJ ;

STRONG, DF ;

KANTIPULY, CJ .

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 1987, 42 (1-2) :75-92

[7] INDUCTIVELY COUPLED PLASMA-MASS SPECTROMETRIC ANALYSIS OF GEOLOGICAL SAMPLES - A CRITICAL-EVALUATION BASED ON CASE-STUDIES [J].

LONGERICH, HP ;

JENNER, GA ;

FRYER, BJ ;

JACKSON, SE .

CHEMICAL GEOLOGY, 1990, 83 (1-2) :105-118

[8]

LONGERICH HP, 1986, CAN J SPECTROSC, V31, P111

[9]

LONGERICH HP, 1992, ICP INFORM NEWSL, V18, P32

[10] PREPARATION OF HYDROFLUORIC, HYDROCHLORIC, AND NITRIC ACIDS AT ULTRALOW LEAD LEVELS [J].

MATTINSON, JM .

ANALYTICAL CHEMISTRY, 1972, 44 (09) :1715-+

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