TEMPERATURE-DEPENDENCE OF SELF-BROADENING OF AMMONIA TRANSITIONS IN THE NU(2) BAND

被引：10

作者：

BALDACCHINI, G ^{[1
]}

BUFFA, G ^{[1
]}

CIUCCI, A ^{[1
]}

DAMATO, F ^{[1
]}

TARRINI, O ^{[1
]}

机构：

[1] UNIV PISA,DIPARTIMENTO FIS,I-56100 PISA,ITALY

来源：

JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER | 1995年 / 53卷 / 06期

关键词：

D O I：

10.1016/0022-4073(95)00034-I

中图分类号：

O43 [光学];

学科分类号：

070207 ; 0803 ;

摘要：

Self broadening coefficients have been measured as a function of temperature from 192 to 377 K for five transition lines of the nu(2) band of ammonia at similar to 937 cm(-1). The results have been compared with theoretical calculations performed in the semiclassical impact approximation, and although one hot transition does not fit well in this scheme, there is in general a fairly good agreement. Moreover there is also an experimental and theoretical evidence against the commonly assumed power law for the temperature dependence. More measurements are needed to clarify the position of the hot transitions in this respect and to verify the extent of validity of the power law in general.

引用

页码：671 / 680

页数：10

共 28 条

[1] STATE-TO-STATE ROTATIONAL ENERGY-TRANSFER MEASUREMENTS IN THE V2=1 STATE OF AMMONIA BY INFRARED INFRARED DOUBLE-RESONANCE [J].

ABEL, B ;

COY, SL ;

KLAASSEN, JJ ;

STEINFELD, JI .

JOURNAL OF CHEMICAL PHYSICS, 1992, 96 (11) :8236-8250

[2] PRESSURE BROADENING IN THE MICROWAVE AND INFRA-RED REGIONS [J].

ANDERSON, PW .

PHYSICAL REVIEW, 1949, 76 (05) :647-661

[3] A REVIEW OF EXPERIMENTS AND THEORY FOR COLLISIONAL LINE-SHAPE EFFECTS IN THE ROTOVIBRATIONAL AMMONIA SPECTRUM [J].

BALDACCHINI, G ;

BUFFA, G ;

TARRINI, O .

NUOVO CIMENTO DELLA SOCIETA ITALIANA DI FISICA D-CONDENSED MATTER ATOMIC MOLECULAR AND CHEMICAL PHYSICS FLUIDS PLASMAS BIOPHYSICS, 1991, 13 (06) :719-733

[4] EXPERIMENTAL AND THEORETICAL INVESTIGATION OF SELF-BROADENING AND SELF-SHIFTING OF AMMONIA TRANSITION LINES IN THE NU-2-BAND [J].