PREPARATION OF SILICO-ALUMINO-PHOSPHATES BY THE RAPID CRYSTALLIZATION METHOD AND THEIR CATALYTIC PERFORMANCE IN THE CONVERSION OF METHANOL TO LIGHT OLEFINS

被引：45

作者：

INUI, T

MATSUDA, H

OKANIWA, H

MIYAMOTO, A

机构：

[1] Department of Hydrocarbon Chemistry, Faculty of Engineering, Kyoto University, Sakyo-Ku, Kyoto

来源：

APPLIED CATALYSIS | 1990年 / 58卷 / 02期

关键词：

D O I：

10.1016/S0166-9834(00)82285-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 [物理化学]; 081704 [应用化学];

摘要：

Shape-selective silico-alumino-phosphates, SAPO-34 and SAPO-17, having the chabazite and erionite structure, respectively, were prepared within 4 h of hydrothermal treatment by the rapid crystallization method we have developed. They are highly effective for the selective conversion of methanol to light olefins, such as ethene, propene and butenes. It is shown that these SAPOs are more weakly acidic than typical H-ZSM-5 but more strongly acidic than H-Fe-silicates. © 1990.

引用

收藏

页码：155 / 163

页数：9

相关论文

共 23 条

[1]

REACTIONS ON ZSM-5-TYPE ZEOLITE CATALYSTS [J].

ANDERSON, JR ;

FOGER, K ;

MOLE, T ;

RAJADHYAKSHA, RA ;

SANDERS, JV .

JOURNAL OF CATALYSIS, 1979, 58 (01) :114-130

[2]

CONVERSION OF METHANOL AND OTHER O-COMPOUNDS TO HYDROCARBONS OVER ZEOLITE CATALYSTS [J].

CHANG, CD ;

SILVESTRI, AJ .

JOURNAL OF CATALYSIS, 1977, 47 (02) :249-259

[3]

DIFFUSION STUDIES IN ZEOLITES AND RELATED SOLIDS BY GAS CHROMATOGRAPHIC TECHNIQUES [J].

EBERLY, PE .

INDUSTRIAL & ENGINEERING CHEMISTRY FUNDAMENTALS, 1969, 8 (01) :25-&

[4]

EBERLY PE, 1979, ZEOLITE CHEM CATALYS, P392

[5]

CONSIDERABLE REDUCTION IN CRYSTALLIZATION TIME IN THE PREPARATION OF A NEW TYPE OF ZEOLITE CATALYST FOR OLEFIN SYNTHESIS FROM METHANOL [J].

INUI, T ;

ISHIHARA, T ;

TAKEGAMI, Y .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1981, (18) :936-937

[6]

OLEFIN SYNTHESIS FROM METHANOL ON A MODIFIED ZEOLITE CATALYST [J].

INUI, T ;

ISHIHARA, T ;

MORINAGA, N ;

TAKEUCHI, G ;

MATSUDA, H ;

TAKEGAMI, Y .

INDUSTRIAL & ENGINEERING CHEMISTRY PRODUCT RESEARCH AND DEVELOPMENT, 1983, 22 (01) :26-30

[7]

HIGHLY SELECTIVE SYNTHESIS OF LIGHT OLEFINS FROM METHANOL ON A NOVEL FE-SILICATE [J].

INUI, T ;

MATSUDA, H ;

YAMASE, O ;

NAGATA, H ;

FUKUDA, K ;

UKAWA, T ;

MIYAMOTO, A .

JOURNAL OF CATALYSIS, 1986, 98 (02) :491-501

[8]

RAPID SYNTHESIS OF ZEOLITE CATALYSTS FOR METHANOL TO OLEFIN CONVERSION BY THE PRECURSOR HEATING METHOD [J].

INUI, T ;

MORINAGA, N ;

TAKEGAMI, Y .

APPLIED CATALYSIS, 1983, 8 (02) :187-197

[9]

INUI T, 1986, APPL CATAL, V24, P257, DOI 10.1016/S0166-9834(00)81274-9

[10]

EFFECTS OF SEED MATERIALS ON A ZEOLITE AND ITS PERFORMANCE OF METHANOL CONVERSION [J].

INUI, T ;

MORINAGA, N ;

ISHIHARA, T ;

KANIE, T ;

TAKEGAMI, Y .

JOURNAL OF CATALYSIS, 1983, 79 (01) :176-184