SURFACE AND BULK PROPERTIES OF MECHANICALLY ACTIVATED ZINC-SULFIDE

被引：36

作者：

BALAZ, P

BASTL, Z

BRIANCIN, J

EBERT, I

LIPKA, J

机构：

[1] CZECHOSLOVAK ACAD SCI, J HEYROVSKY INST PHYS CHEM & ELECTROCHEM, CS-18223 PRAGUE, CZECHOSLOVAKIA

[2] SLOVAK ACAD SCI, INST EXPTL MET, CS-04357 KOSICE, CZECHOSLOVAKIA

[3] CENT INST PHYS CHEM, BERLIN, GERMANY

[4] SLOVAK UNIV TECHNOL BRATISLAVA, CS-81219 BRATISLAVA, CZECHOSLOVAKIA

来源：

JOURNAL OF MATERIALS SCIENCE | 1992年 / 27卷 / 03期

关键词：

D O I：

10.1007/BF02403874

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

BET, scanning electron microscopy, X-ray photoelectron, infrared, X-ray diffraction and Mossbauer spectroscopy methods were used to identify changes in surface, structural and spectroscopic properties of sphalerite produced by mechanical activation. Activated samples exhibit amorphization of crystallographic structure of the mineral, as well as of hyperfine structure of the accessory manganese. The presence of a new magnetic phase was disclosed in the samples activated for longer periods of time. Changes in structure are accompanied by mechanochemical oxidation of the surface layer of sphalerite.

引用

页码：653 / 657

页数：5

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