TRIGONAL-MONOPYRAMIDAL M(III) COMPLEXES OF THE TYPE [M(N3N)] (M = TI, V, CR, MN, FE N3N = [(TBUME2SI)NCH2CH2]3N)

被引：123

作者：

CUMMINS, CC ^{[1
]}

LEE, J ^{[1
]}

SCHROCK, RR ^{[1
]}

DAVIS, WD ^{[1
]}

机构：

[1] MIT,DEPT CHEM,CAMBRIDGE,MA 02139

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 11期

关键词：

D O I：

10.1002/anie.199215011

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The bulkiness and multidenticity of the ligands stabilize the unusual trigonal-monopyramidal coordination geometry of the title complexes, which were prepared by "reductive" (Ti, V), "direct" (Cr, Fe), and "oxidative" (Mn) routes. The V complex was characterized by X-ray crystallography (structure shown here).

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页码：1501 / 1503

页数：3

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