THE THERMAL REARRANGEMENT OF 6-METHYL-6-VINYLBICYCLO[3.2.0]HEPTANE

被引：3

作者：

GLASS, TE ^{[1
]}

LEBER, PA ^{[1
]}

机构：

[1] FRANKLIN & MARSHALL COLL,POB 3003,LANCASTER,PA 17604

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 08期

关键词：

D O I：

10.1016/S0040-4039(00)88732-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Gas-phase pyrolysis of the endo-vinyl epimer (1A) of the title compound at 275°C affords predominantly 3-(2-methyl-2-butenyl)cyclopentene (presumably the Z isomer), a direct [1,5]-hydrogen shift product, whereas the exo-vinyl epimer (1B) favors the fragmentation products, cyclopentene and isoprene. © 1990.

引用

页码：1085 / 1088

页数：4

共 6 条

[1] PREPARATION OF 7-METHYL-7-VINYLBICYCLO[3.2.0]HEPT-2-ENE VIA CYCLOBUTANONE REDUCTION [J].