ESR SPECTROSCOPIC OBSERVATION OF ALKANE AGGREGATION AND OF HYDROGEN PROTON-TRANSFER BETWEEN ALKANE RADICAL CATIONS AND ALKANE MOLECULES IN CCL3F MATRICES AT CRYOGENIC TEMPERATURES

被引：16

作者：

LUYCKX, G ^{[1
]}

CEULEMANS, J ^{[1
]}

机构：

[1] KATHOLIEKE UNIV LEUVEN,DEPT CHEM,CELESTIJNENLAAN 200F,B-3001 LOUVAIN,BELGIUM

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 15期

关键词：

D O I：

10.1039/c39910000988

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Alkanes form small aggregates in CCl3F matrices at cryogenic temperatures; upon gamma-irradiation, both hole transfer to these aggregates and hydrogen-proton transfer between alkane radical cations and alkane molecules occurs.

引用

页码：988 / 989

页数：2

共 16 条

[1] THE RADIATION-CHEMISTRY OF CRYSTALLINE ALKANES [J].

CHAPPAS, WJ ;

SILVERMAN, J .

RADIATION PHYSICS AND CHEMISTRY, 1980, 16 (06) :437-443

[2]

DOLIVO G, 1985, Z NATURFORSCH A, V40, P52

[3] ELECTRON-SPIN-RESONANCE, STRUCTURE, AND REACTIONS OF SPECIFICALLY DEUTERIUM-LABELED PENTANE CATIONS IN X-IRRADIATED FREON MATRICES [J].

DOLIVO, G ;

LUND, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1985, 89 (19) :3977-3984

[4] COMPARISON OF RADICAL AND NONRADICAL PROCESSES IN CONDENSED-PHASE RADIOLYSIS OF N-HEXADECANE [J].

FALCONER, WE ;

SALOVEY, R .

JOURNAL OF CHEMICAL PHYSICS, 1966, 44 (09) :3151-&

[5] THE FATE OF PRIMARY CATIONS IN RADIOLYSIS OF ALKANES AS STUDIED BY ELECTRON-SPIN-RESONANCE [J].

IWASAKI, M ;

TORIYAMA, K ;

NUNOME, K .

RADIATION PHYSICS AND CHEMISTRY, 1983, 21 (1-2) :147-156

[6] ELECTRON-SPIN RESONANCE STUDY OF ELECTRONIC AND GEOMETRICAL STRUCTURES OF C2H6+ AND OTHER SIMPLE ALKANE CATIONS AT 4.2 K - POSSIBLE EVIDENCE FOR JAHN-TELLER DISTORTION [J].

IWASAKI, M ;

TORIYAMA, K ;

NUNOME, K .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (12) :3591-3592

[7] CHEMISTRY OF POSITIVE IONS .3. RADIATION CHEMISTRY OF SOLID N-HEXANE AT 77DEGREESK [J].

KEVAN, L ;

LIBBY, WF .

JOURNAL OF CHEMICAL PHYSICS, 1963, 39 (05) :1288-&

[8] D-ISOTOPE-LABELED NORMAL-BUTANE CATIONS IN (CF3CCL3) AND IN (CF2CLCFCL) - STRUCTURE AND REACTIONS AT LOW-TEMPERATURE [J].

LINDGREN, M ;

LUND, A ;

DOLIVO, G .

CHEMICAL PHYSICS, 1985, 99 (01) :103-110

[9] ELECTRON-SPIN-RESONANCE AND STRUCTURE OF SPECIFICALLY DEUTERATED N-ALKANE CATIONS IN HALOGENATED MATRICES [J].

LUND, A ;

LINDGREN, M ;

DOLIVO, G ;

TABATA, M .

RADIATION PHYSICS AND CHEMISTRY, 1985, 26 (05) :491-498

[10] PHOTOINDUCED AND THERMAL-REACTIONS OF MOLECULAR SIGMA-RADICAL CATIONS OF SOME BRANCHED ALKANES IN LOW-TEMPERATURE MATRICES - AN ELECTRON-SPIN-RESONANCE STUDY [J].

NUNOME, K ;

TORIYAMA, K ;

IWASAKI, M .

CHEMICAL PHYSICS LETTERS, 1984, 105 (04) :414-419

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