THERMODYNAMIC PERTURBATION-THEORY - STICKY CHAINS AND SQUARE-WELL CHAINS

被引:80
作者
BANASZAK, M [1 ]
CHIEW, YC [1 ]
RADOSZ, M [1 ]
机构
[1] RUTGERS UNIV,DEPT CHEM & BIOCHEM ENGN,PISCATAWAY,NJ 08855
来源
PHYSICAL REVIEW E | 1993年 / 48卷 / 05期
关键词
D O I
10.1103/PhysRevE.48.3760
中图分类号
O35 [流体力学]; O53 [等离子体物理学];
学科分类号
070204 ; 080103 ; 080704 ;
摘要
We extend Wertheim's first-order thermodynamic perturbation theory [J. Chem. Phys. 87, 7323 (1987)] to sticky chains and square-well chains. The predicted compressibility factors for square-well chains are found to agree with Monte Carlo data. We demonstrate that the effect of chain connectivity is to reduce the attraction contributions to the compressibility factor and to the critical temperatures.
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页码:3760 / 3765
页数:6
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