FULLERENE C-60 AND C-70 PHOTOSENSITIZED OXYGENATION OF OLEFINS

被引：64

作者：

ORFANOPOULOS, M

KAMBOURAKIS, S

机构：

[1] Department of Chemistry, University of Crete, 71110 Iraklion, Crete

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 12期

关键词：

D O I：

10.1016/S0040-4039(00)73202-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

C-60 and C-70 sensitize the photooxygenation of 2-methyl-2-butene as well as (E)-2-methyl-2-pentene-1,1,1-d(3) by the intermediacy of singlet oxygen. Addition of DABCO reduces substantially the rate of photooxygenation. The regio- and stereoselectivity of these reactions are reported

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页码：1945 / 1948

页数：4

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