REVOLVENEYNES - NOVEL ENEYNEPARACYCLOPHANES BY SEQUENTIAL PALLADIUM COUPLING

被引:32
作者
ROMERO, MA [1 ]
FALLIS, AG [1 ]
机构
[1] UNIV OTTAWA,OTTAWA CARLETON CHEM INST,DEPT CHEM,OTTAWA K1N 6N5,ON,CANADA
关键词
D O I
10.1016/S0040-4039(00)76948-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The synthesis and initial study of a new series of eneyne-bridged cyclophanes (revolveneynes) are described in which the phenyl rings are free to rotate within the cavity. Either palladium coupling or oxidative dimerization provided rapid access to [14], [6.6] and [8.8] phane systems.
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页码:4711 / 4714
页数:4
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