RADIATION-INDUCED COPOLYMERIZATION OF CIS-[PDCL2(CN(CH2)3-OC(O)-CH=CH2)2] - A NOVEL ROUTE TO ORGANOMETALLIC CROSS-LINKED COPOLYMERS USEFUL FOR CATALYTIC APPLICATIONS

被引：11

作者：

CORAIN, B

ZECCA, M

SAM, FO

PALMA, G

LORA, S

机构：

[1] UNIV PADUA,DEPARTIMENTO CHIM FIS,I-35131 PADUA,ITALY

[2] CNR,IST FOTOCHIM & RADIAZ ALTA ENERGIA,I-35020 LEGNANO,ITALY

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1990年 / 29卷 / 04期

关键词：

D O I：

10.1002/anie.199003841

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new polymer has been shown to be an effective hydrogenation catalyst: specifically, the polymer that results from copolymerization (through γ‐ irradiation) of the isocyanide complex 1 with dimethylacrylamide in the presence of N,N′‐methylenebisacrylamide. The PdII centers are initially pre‐hydrogenated to Pd0, after which the catalyst becomes stable, especially with respect to the loss of metallic centers. (Formula Presented.) Copyright © 1990 by VCH Verlagsgesellschaft mbH, Germany

引用

页码：384 / 385

页数：2

共 10 条

[1]

CARENZA M, 1988, RADIAT PHYS CHEM, V31, P657

[2] [PDCL2(PPH3)(CN-(CH2)3-O-C(O)-CH=CH2)] AND [PDCL2(PPH3)(C-N(H)-CH2-CH2-N-(CH2)3-O-C(O)-CH=CH2)] - PROTOTYPES OF NOVEL ORGANOMETALLIC VINYL MONOMERS [J].

CASELLATO, U ;

CORAIN, B ;

ZECCA, M ;

MICHELIN, RA ;

MOZZON, M ;

GRAZIANI, R .

INORGANICA CHIMICA ACTA, 1989, 156 (02) :165-167

[3]

CORAIN B, 1989, ADV METAL CARBENE CH, P75

[4]

CORAIN B, 1990, MAKROMOL CHEM-RAPID, V10, P697

[5]

CORAIN B, 1990, J MOL CATAL, V55, P209

[6]

HARTLEY FR, 1985, SUPPORTED METAL COMP

[7]

MALATESTA L, 1969, ISOCANIDE COMPLEXES, P158

[8]

Parshall G.W., 1980, HOMOGENEOUS CATALYSI

[9]

PITTMANN CU, 1988, 1987 APPL POL P AM C

[10]

SINGLETON E, 1983, ADV ORGANOMET CHEM, V22, P209

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