THE VISCOSITY OF SUPERCOOLED FRUCTOSE AND ITS GLASS-TRANSITION TEMPERATURE

被引：58

作者：

OLLETT, AL

PARKER, R

机构：

[1] AFRC Institute of Food Research, Norwich Laboratory, Norwich, NR4 7UA, Colney Lane

来源：

JOURNAL OF TEXTURE STUDIES | 1990年 / 21卷 / 03期

关键词：

D O I：

10.1111/j.1745-4603.1990.tb00484.x

中图分类号：

TS2 [食品工业];

学科分类号：

0832 ;

摘要：

The viscosities of supercooled liquid fructose and glucose are measured between a lower viscosity limit corresponding to 95°C and an upper limit of about 106 Pa.s. The glass transition temperature of fructose is estimated from the viscosity data using different extrapolation procedures. The Vogel‐Tamman‐Fulcher and power‐law equations gave estimates of 283K and 289K, respectively and the Williams‐Landel‐Ferry equation 286K. These values are in agreement with recent calorimetric determinations of the glass transition temperature. Copyright © 1990, Wiley Blackwell. All rights reserved

引用

收藏

页码：355 / 362

页数：8

相关论文

共 15 条

[1] VISCOSITY TEMPERATURE FUNCTION FOR SORBITOL FROM COMBINED VISCOSITY AND DIFFERENTIAL SCANNING CALORIMETRY STUDIES [J].

ANGELL, CA ;

STELL, RC ;

SICHINA, W .

JOURNAL OF PHYSICAL CHEMISTRY, 1982, 86 (09) :1540-1542

[2] THE IRREVERSIBLE APPROACH TO EQUILIBRIUM IN GLASSES [J].

DAVIES, RO ;

JONES, GO .

PROCEEDINGS OF THE ROYAL SOCIETY OF LONDON SERIES A-MATHEMATICAL AND PHYSICAL SCIENCES, 1953, 217 (1128) :26-42

[3]

FINEGOLD L, 1989, J CHEM SOC FARADAY T, V85, P2445

[4] THE TEMPERATURE-DEPENDENCE OF RELAXATION PROCESSES [J].

HILL, RM ;

DISSADO, LA .

JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1982, 15 (25) :5171-5193

[5]

Levine H, 1988, WATER SCI REV, V3

[6] SECONDARY RELAXATIONS AND THE STRUCTURE OF GLASS [J].

MURTHY, SSN .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS II, 1989, 85 :581-596

[7] ASPECTS OF THE GLASS-TRANSITION BEHAVIOR OF MIXTURES OF CARBOHYDRATES OF LOW-MOLECULAR-WEIGHT [J].

ORFORD, PD ;

PARKER, R ;

RING, SG .

CARBOHYDRATE RESEARCH, 1990, 196 :11-18

[8] EFFECT OF WATER AS A DILUENT ON THE GLASS-TRANSITION BEHAVIOR OF MALTO-OLIGOSACCHARIDES, AMYLOSE AND AMYLOPECTIN [J].

ORFORD, PD ;

PARKER, R ;

RING, SG ;

SMITH, AC .

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 1989, 11 (02) :91-96

[9] The viscosity of undercooled liquid glucose [J].

Parks, George S. ;

Barton, Lois E. ;

Spaght, Monroe E. ;

Richardson, J. Wilfred .

PHYSICS-A JOURNAL OF GENERAL AND APPLIED PHYSICS, 1934, 5 (01) :193-199

[10] Studies on glass IV Some viscosity data on liquid glucose and glucose-glycerol solutions [J].

Parks, GS ;

Gilkey, WA .

JOURNAL OF PHYSICAL CHEMISTRY, 1929, 33 :1428-1437