NOVEL REACTIVITY OF STABILIZED METHYLENETRIBUTYLPHOSPHORANE - A NEW MITSUNOBU REAGENT

被引：75

作者：

TSUNODA, T

OZAKI, F

ITO, S

机构：

[1] Faculty of Pharmaceutical Sciences, Tokushima Bunri University, Tokushima

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 28期

关键词：

D O I：

10.1016/S0040-4039(00)73326-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cyanomethylenetributylphosphorane was shown to mediate the direct condensation of alcohols with O- and N-nucleophiles. A secondary alcohol, 2-octanol, reacted satisfactorily with Walden inversion of its carbinyl carbon.

引用

页码：5081 / 5082

页数：2

共 5 条

[1]

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[2]

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TSUNODA, T ;

OTSUKA, J ;

YAMAMIYA, Y ;

ITO, S .

CHEMISTRY LETTERS, 1994, (03) :539-542

[5] 1,1'-(AZODICARBONYL)DIPIPERIDINE-TRIBUTYLPHOSPHINE, A NEW REAGENT SYSTEM FOR MITSUNOBU REACTION [J].

TSUNODA, T ;

YAMAMIYA, Y ;

ITO, S .

TETRAHEDRON LETTERS, 1993, 34 (10) :1639-1642

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