A COMPARATIVE-STUDY OF [CO(NH3)(5)ONO]XY[--][CO(NH3)(5)NO2]XY (XY=CL-2, BR-2, I-2, (NO3)(2) CL NO3) SOLID-STATE ISOMERIZATION KINETICS

被引：16

作者：

DULEPOV, VE ^{[1
]}

BOLDYREVA, EV ^{[1
]}

机构：

[1] NOVOSIBIRSK STATE UNIV,NOVOSIBIRSK 630090,RUSSIA

来源：

REACTION KINETICS AND CATALYSIS LETTERS | 1994年 / 53卷 / 02期

关键词：

D O I：

10.1007/BF02073033

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Quantitative IR investigation of solid-state [Co(NH3)(5) ONO]XY <---->- [Co(NH3)(5)NO2]XY (XY=Cl-2, Br-2, I-2, (NO3)(2), Cl; NO3) linkage isomerization in KBr pellets has shown 3 the kinetics to depend upon the outer-sphere anion. The red shift of the nu(5)(ONO) band during isomerization is a 5 linear function of transformation degree.

引用

页码：289 / 296

页数：8

共 16 条

[1]

ADELL B, 1952, Z ANORG ALLG CHEM, V49, P271

[2]

BEATTIE IR, 1952, T FARADAY SOC, V52, P1590

[3]

Boldyreva E. V., 1982, IZV SIB OTD AN KHIM, V5, P18

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