COORDINATION CHEMISTRY OF PHOSPHORYL COMPOUNDS .I. LANTHANIDE COMPLEXES OF HEXAMETHYL PHOSPHORAMIDE

被引:42
作者
DONOGHUE, JT
PETERS, DA
机构
[1] Department of Chemistry, University of Arkansas, Fayetteville
来源
JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY | 1969年 / 31卷 / 02期
关键词
D O I
10.1016/0022-1902(69)80490-2
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Complexes of lanthanides of the type LnCl3-3HMPA have been prepared and characterized by means of analytical, conductivity and infrared spectral studies (HMPA = O = P[N(CH3)2]3). It has been found that the lanthanides exhibit the unusual coordination number of six in these compounds. Results also indicate that the ligand is coordinated via its phosphoryl oxygen atom. © 1969.
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页码:467 / &
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