SYNTHESIS OF "2-HYDROXY-3-METHYLCYCLOPENT-2-ENONE FROM METHYL ACRYLATE

被引：14

作者：

COOKSON, RC

SMITH, SA

机构：

[1] Department of Chemistry, The University

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1979年 / 10期

关键词：

D O I：

10.1039/p19790002447

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The title compound was prepared in 55% yield from the dimer of methyl acrylate, dimethyl 2-methylenepentanedioate. The crucial step in the synthesis involved silica gel as a reaction medium.

引用

页码：2447 / 2448

页数：2

共 14 条

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[4] CONVERSION OF DIALDEHYDES INTO CYCLIC ALPHA-KETOLS BY THIAZOLIUM SALTS - SYNTHESIS OF CYCLIC 2-HYDROXY-2-ENONES
COOKSON, RC
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JAIN, TC
BANKS, CM
MCCLOSKEY, JE
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[7] KENDE AS, 1973, TETRAHEDRON LETT, P697
[8] LANGINLANTERI MT, 1976, SYNTHESIS-STUTTGART, P541
[9] A NEW SYNTHESIS OF 3-ALKYL-2-CYCLOPENTEN-2-OL-1-ONES
LEIR, CM
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1970, 35 (10) : 3203 - &
[10] NAGATO N, 1973, Patent No. 7386816

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