SYNTHESIS OF CATIONIC (PI-ALLYL)RHENIUM COMPLEXES AND THEIR REACTIONS WITH CARBON NUCLEOPHILES

被引：21

作者：

CASEY, CP

YI, CS

机构：

[1] Department of Chemistry, University of Wisconsin, Madison

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 09期

关键词：

D O I：

10.1021/om00159a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The cationic (π-allyl)rhenium complexes C5H5(CO)2Re(η3-CH2CHCH2)+PF6- (2) and C5H5(CO)2Re-(η3-CH2CHCHCH3)+PF6- (3) were synthesized from rhenium alkene complexes C5H5(CO)2Re(π2-CH2=CHCH3) (1) and C5H5(CO)2Re(π2-cis -CH3CH=CHCH3) (4) by hydride abstraction with (C6H5)3C+PF6-. Allyl complexes 2 and 3 reacted with carbon nucleophiles to produce elaborated rhenium alkene complexes. © 1990, American Chemical Society. All rights reserved.

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页码：2413 / 2414

页数：2

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