CHEMISTRY OF ORGANOSILICON COMPOUNDS .281. PHOTOINDUCED ELECTRON-TRANSFER REACTION OF POLYSILANES - INTRAMOLECULAR TRAPPING OF A TRANSIENT SILYL RADICAL CATION WITH A NUCLEOPHILE

被引：44

作者：

NAKADAIRA, Y

SEKIGUCHI, A

FUNADA, Y

SAKURAI, H

机构：

[1] TOHOKU UNIV, FAC SCI, DEPT CHEM, SENDAI, MIYAGI 980, JAPAN

[2] TOHOKU UNIV, FAC SCI, ORGANOSILICON RES LAB, SENDAI, MIYAGI 980, JAPAN

来源：

CHEMISTRY LETTERS | 1991年 / 02期

关键词：

D O I：

10.1246/cl.1991.327

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The radical cation, produced in photo-induced electron transfer of polysilanyl alkanols, can be trapped efficiently intramolecularly with the hydroxyl group. The silyl radical generated in the process is trapped by the solvent employed. A good Hammett relationship is observed in aryldisilanylalkanols between the relative reactivities of the Si-Si bond and sigma+ constants of the substituent on the aryl group.

引用

页码：327 / 330

页数：4

共 10 条

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