STRUCTURAL DETERMINATION OF THE OZONIDES DERIVED FROM MONO-SUBSTITUTED ALKENES

被引：10

作者：

HON, YS

LING, L

CHANG, RC

CHU, KP

机构：

[1] Institute of Chemistry, Academia Sinica, Nankang

来源：

HETEROCYCLES | 1991年 / 32卷 / 03期

关键词：

D O I：

10.3987/COM-91-5663

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The structures of 1,2,4-trioxolanes (ozonides) (2a-2f) derived from mono-substituted alkenes (1a-1f), respectively, were determined by spectroscopic methods, such as H-1-nmr, C-13-nmr, ir, two-dimensional nmr, and mass spectra. The coupling constant of the geminal protons on the trioxolane ring is zero. This unusual coupling constant resulted from the electronegativity of two oxygen atoms near the geminal protons.

引用

页码：437 / 442

页数：6

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